Dielectric Polarization in Electric Fields

In an external electric field, the positive and negative charges of a non-polar molecule are displaced in opposite directions. The displacement stops when the external force on the constituent charges of the molecule is balanced by the restoring force (due to internal fields in the molecule). The non-polar molecule thus develops an induced dipole moment.

A dielectric with polar molecules also develops a net dipole moment in an external field, but for a different reason. In the absence of any external field, the different permanent dipoles are oriented randomly due to thermal agitation; so the total dipole moment is zero. When an external field is applied, the individual dipole moments tend to align with the field.